Abstract:
In  recent  years,  the  increasing  threat  to  ground  water  quality  due  to  human  activities  has become  a  matter  of  great  concern.  Jhansi  area  sprawling  and  incoming  of  new  industries  around it  have  increased  concern  about  the  fate  of  groundwater  quality.  The  report  presents  an assessment  of  hydrochemistry  and  groundwater  quality  index  of  Moth  block  of  district  Thansi. Twenty  groundwater  samples  from  different  places  of  study  area  (Moth  block)  were  collected and  analyzed  for  pH,  Electrical  Conductivity  (EC),  Total  Dissolved  Solids  (TDS),  Sodium  (Na+), Potassium  (K+),  Total  Hardness  (TH),  Calcium  (Ca2+),  Magnesium  (Mg2+),  Bicarbonate  (HCO3), Sulphate  (S042-),  Nitrate  (N031,  Fluoride  (F-)  and  Chloride  (cn.  The  samples  were  analysed following  standard  method. 
The  variations  observed  were  in  pH  (7.16-7.87),  EC  (460-2106 	1S/cm),  TDS  (261.82-1360 mg/L),  Na+  (25.65-209.37  mg/L),  K+  (0.43-12.31  mg/L),  TH  (75.57-792.77  mg/L),  Ca2+  (10.90-
256.89  mg/L),  Mg2+  (8.34-75.89  mg/L),  HCO3(253.25-612.75  mg/L),  S042-  (0.61-247.12  mg/L), NO3  (2.64-127.61  mg/L) (0.36-6.11  mg/L)  and  D-(3.52-4.23.25  mg/L). 
Chemical  analyses  of  water  samples  showed  that  calcium  and  bicarbonate  are  the  dominant cation  and  anion,  respectively.  The  water  type  is  Ca-Mg-HCO3  based  on  hydro-chemical  faces using  Piper's  diagram.  The  results  were  compared  with  the  drinking  water  standard  (BIS  10500: 2012)  to  assess  the  suitability  for  drinking  purpose  and  water  quality  indicators  viz.,  sodium adsorption  ratio  (SAR)  and  percent  sodium  (%Na)  were  determined  to  assess  the  suitability  for irrigation  purpose.  The  results  revealed  that  the  groundwater  in  the  study  area  is  suitable  for drinking  and  irrigation  purposes. 
Bacteriological  analysis  variations  observed  were  in  TC  (0-1100  per  100  ml  MPN)  and  FC  (0-
460  per  100  ml   MPN).  As  we  know  that  according  to  BIS  TC  and  FC  in  ground  water  shall  not be  detectable  in  any  100  ml  sample  for  drinking  purpose. 
Toxicity  of  a  metal  depends  on  its  concentration,  which  adversely  affects  any  biological  activity. Almost  all  the  metals  are  toxic  at  higher  concentration;  few  of  them  are  toxic  in  low concentration  quantity  but  few  others  are  even  in  trace  e.g.  As,  Pb,  Hg  ,  Cd,  etc.  The  presence  of such  metals  in  ground  water  is  a  subject  of  serious  concern.  Groundwater  which  contains  higher amount  of  metals  and  large  or  trace  quantity  of  toxic  metals,  affects  health  to  a  great  extent  when 
iv 
 
it  is  used  for  drinking  and  domestic  purposes.  The  impact  of  trace  metal  in  drinking  water  is generally  cumulative,  by  which  the  prolonged  use  of  such  waters  is  dangerous  for  health.  Hence the  measurement  of  trace  elements  concentration  and  analysis  of  their  periodicity  of  fluctuation and  trend  is  necessary.  The  study  revealed  that  the  concentrations  of  Al,  Cr,  Fe,  Mn,  Ni  and  Pb crossed  the  minimum  permissible  limits  of  BIS  in  the  most  of  sites  and  alarming  condition.  The concentration  of  As,  Cd,  Co,  Cu  and  Zn  The  maximum  concentration  of  Al,  Cr,  Fe,  Mn,  Ni  and Pb  were  recorded  as  4.927,  0.0545,  16.822,  0.354,  0.030,  and  0.011  respectively. 
For  the  Drinking  Water  Quality  Index  observed 	45%,  35%,  20%  collected  samples  were  under poor,  marginal,  fair  designation  respectively.  The  collected  samples  show  45%,  35%,  15%,  5% belong  to  marginal,  poor,  fair,  good  designation  respectively  in  the  terms  of  HWQI  where  the collected  samples  of  study  area  were  60%,20%,  10%,  10%  belong  to  marginal,  poor,  fair,  good designation  respectively  in   the  terms  of  AWQI.  The  residents  of  these  areas  should  be  provided with  some  alternate  source  of  water  for  drinking  or  the  available  groundwater  should  be  utilized after  treatment.