Abstract:
The paper presents a study of zinc adsorption using the experimental data on bed sediments of River Hindon in western Uttar Pradesh (India).
The effect of various operating variables, viz., initial concentration, solution pH, sediment dose, contact time, and particle size, have been
studied. The optimum contact time needed to reach equilibrium was of the order of 60 min and was independent of initial concentration of zinc
ions. The extent of adsorption increased with an increase of pH. Furthermore the adsorption of zinc increases with increasing adsorbent doses
and decreases with the adsorbent particle size. The content of iron, manganese and organic matter in various fraction of sediment decreases
with increasing particle size indicating the possibility of the two geochemical phases to act as the active support material for the adsorption of
zinc ions. The adsorption data follows both Langmuir and Freundlich adsorption models. Isotherms were used to determine thermodynamic
parameters, viz., free energy change, enthalpy change and entropy change. The negative values of free energy change indicate spontaneous
nature of the adsorption while positive values of enthalpy change suggest the endothermic nature of the adsorption of zinc on bed sediment
of the River Hindon. The positive values of entropy change indicate randomness at the solid/solution interface.
